At an extraordinary joint news conference, Obama chided China on its treatment of dissidents and insisted hacking attacks on US firms must stop, even as he thanked Xi for his commitment on climate change.
The world's top two economic powers are also its biggest polluters, and campaigners hailed their commitment to reduce emissions as a key step toward a global climate pact before the end of the year.
This achievement was all the more remarkable given the tensions over industrial espionage and China's aggressive moves to seize disputed territory in the South China Sea.
The red carpet and full ceremonial honours that welcomed Xi to the White House underlined the importance of the great powers' relationship, but the leaders made no effort to conceal their differences.
The two delegations promised not to spy on each other's private enterprises for commercial gain, but here again, Obama used tough language, declaring: "I indicated it has to stop."
Xi protested that "China strongly opposes and combats the theft of commercial secrets and other kinds of hacking attacks".
The Chinese leader also firmly pushed back on human rights criticism, warning that reform would come on China's own timetable and without undermining its stability.
"We must recognise that countries have different historical processes and realities, that we need to respect people of all countries in the rights to choose their own path independently," he said.
There was also a sharp exchange over China's bid to extend its sovereignty over the South China Sea by building bases on reclaimed islands in areas disputed by Washington's southeast Asian allies.
"Islands in the South China Sea, since ancient times, are China's territory," Xi declared. "We have the right to uphold our own territorial sovereignty and lawful and legitimate maritime rights and interests."
Obama said the disputes must be settled in accordance with international statutes, noting the US was not a claimant.
Both countries signed a "joint vision" ahead of December's UN climate summit in Paris, and China committed to a domestic "cap and trade" carbon exchange. China will also set aside US$3.1 billion ($4.85 billion) to help developing countries fight climate change.
"If the world's two largest economies, energy consumers and carbon emitters come together like this, then there is no reason for other countries, whether developed or developing, to not do so as well," Obama said.
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